(Azido-κN){(E)-2-[1-(pyridin-2-yl)ethylideneamino]phenolato-κ3 N,N′,O}copper(II)
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چکیده
In the title complex, [Cu(C13H11N2O)(N3)], the Cu(II) cation is four-coordinated by an N2O donor set of the tridentate Schiff base ligand and by the terminal N atom of the azide anion, forming a slightly distorted square-planar configuration.
منابع مشابه
(Azido-κN)[6-methoxy-2-(2-pyridylmethyliminomethyl)phenolato-κ3 N,N′,O 1]copper(II)
The title compound, [Cu(C(14)H(13)N(2)O(2))(N(3))], is a monomeric neutral complex with one unsymmetrical 6-meth-oxy-2-(2-pyridylmethyl-imino-meth-yl)phenolate Schiff base ligand and one azide ligand. The mol-ecules are connected by a combination of two π-π inter-actions [centroid-centroid distances 3.359 (3) and 3.378 (2) Å] and one C-H⋯N hydrogen bond into a two-dimensional supra-molecular ne...
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The Pb(II) atom in the polymeric title compound, {[Pb(C(13)H(11)N(4)O)]ClO(4)}(n), is coordinated by the N'-[1-(pyridin-2-yl-κN)ethyl-idene]isonicotinohydrazidate ligand via its O,N,N'-donors and simultaneously bridged by a neighbouring ligand via the pyridin-2-yl N atom. The resultant supra-molecular chain is a zigzag along the a axis. The stereochemistry of the Pb(II) atom is defined by an N(...
متن کاملBis{μ-2-[(pyridin-2-yl)iminomethyl]phenolato}bis[(2-formylphenolato)copper(II)]
The asymmetric unit of the title compound, [Cu(2)(C(12)H(9)N(2)O)(2)(C(7)H(5)O(2))(2)], contains two independent (2-formyl-phen-olato){2-[(pyridin-2-yl)imino-meth-yl]phenolato}copper(II) mol-ecules that form pseudocentrosymmetric dimers via inter-actions between the Cu and pyridyl N atoms of independent monomers. The square-planar geometry of the Cu atoms in the monomer thus becomes square-base...
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In the title complex, [Cu(C(9)H(7)N(2)O(2)S)(2)], the Cu(II) ion, located on an inversion center, adopts an N(2)O(2) square-planar coord-ination. The 2-(5-methyl-sulfanyl-1,3,4-oxadiazol-2-yl)phenolate ligand is chelated to the central Cu(II) ion in an N,O-bidentate manner.
متن کامل{(E)-4-Hydroxy-N′-[phenyl(pyridin-2-yl-κN)methylidene]benzohydrazide-κ2 N′,O}bis(nitrato-κ2 O,O′)copper(II)
In the title compound, [Cu(NO(3))(2)(C(19)H(15)N(3)O(2))], the coordination geometry around the Cu(II) ion can be described as distorted square-pyramidal, with two N atoms and one O atom from an (E)-4-hy-droxy-N'-[phen-yl(pyridin-2-yl)methyl-ene]benzohydrazide ligand and one nitrate O atom in the basal plane and one nitrate O atom at the apical site. The other two nitrate O atoms also bind to t...
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